On the basis of standard electrode potential values,suggest which of the following reactions would take place?

  • A
    $Cu + Zn^{+2} \rightarrow Cu^{+2} + Zn$
  • B
    $Mg + Fe^{+2} \rightarrow Mg^{+2} + Fe$
  • C
    $Br_{2} + 2Cl^{-} \rightarrow Cl_{2} + 2Br^{-}$
  • D
    $Fe + Cd^{+2} \rightarrow Cd + Fe^{+2}$

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Calculate the equilibrium constant at $298 \ K$ for the following reaction and also calculate the maximum work that can be obtained from this cell:
$Mg(s) \ | \ Mg^{2+}(aq) \ || \ Ag^{+}(aq) \ | \ Ag(s)$
Given: $E_{Mg^{2+} \mid Mg}^{o} = -2.37 \ V$ and $E_{Ag^{+} \mid Ag}^{o} = 0.80 \ V$

Calculate the standard cell potentials of galvanic cells in which the following reactions take place:
$(i)$ $2Cr_{(s)} + 3Cd^{2+}_{(aq)} \rightarrow 2Cr^{3+}_{(aq)} + 3Cd_{(s)}$
$(ii)$ $Fe^{2+}_{(aq)} + Ag^{+}_{(aq)} \rightarrow Fe^{3+}_{(aq)} + Ag_{(s)}$
Calculate the $\Delta_r G^\Theta$ and equilibrium constant of the reactions.

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At $25^\circ \text{C}$,given the following data: $Ag_{(s)} + I^-_{(aq)} \rightarrow AgI_{(s)} + e^-$,$E^o = 0.152 \ V$; $Ag_{(s)} \rightarrow Ag^+_{(aq)} + e^-$,$E^o = -0.800 \ V$. What is the value of $\log \ K_{sp}$ for $AgI$? (where $K_{sp} = \text{solubility product}$)

The conductivity of $0.01 \ M$ aqueous acetic acid measured with a conductivity cell of cell constant $0.5 \ cm^{-1}$ at $298 \ K$ is $3.12 \times 10^{-4} \ S$. If the limiting molar conductivities of $H^{+}$ and $CH_3COO^{-}$ at the same temperature are $349$ and $41 \ S \ cm^2 \ mol^{-1}$ respectively,the dissociation constant of acetic acid is

Column $I$ Column $II$
$(A)$. Kohlrausch law can calculate $(P)$. $\frac{\Lambda_m^c}{\Lambda_m^o}$
$(B)$. Molar conductance $\Lambda_m$ $(Q)$. $\frac{1}{R} \times \frac{l}{A}$
$(C)$. Specific conductance $\kappa$ $(R)$. $\Lambda_m^o$ of $Ca_3(PO_4)_2$
$(D)$. Degree of ionization of weak electrolyte $(S)$. $\frac{\kappa \times 1000}{M}$
Which of the following options shows the correct matches?

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